石油化工2011，Vol.40Issue(12)：1370-1374,5.
钴催化剂催化高碳烯烃氢甲酰化反应的研究进展
Development on Cobalt-Catalyzed Hydroformylation of Higher Olefins
摘要
Abstract
In view of the industrial homogeneous cobalt-catalyzed hydroformylation of higher olefins, the innovation of the formation of cobalt hydrotetracarbonyl catalyst and phosphine ligands for the modification of the cobalt catalysts, the present industrial methods for the recovery of cobalt and the development of cobalt-catalyzed higher olefins hydroformylation in the liquid/liquid biphasic system were summarized in this review. Cobalt-catalyzed hydroformylation in aqueous/organic biphase system makes the easy catalyst recycling as well as maintaining the catalyst activity and selectivity, so exploration of excellent aqueous/organic biphase catalytic system is still an important topic of R & D in the future.关键词
高碳烯烃/氢甲酰化/钴催化剂/液液两相催化Key words
higher olefins/ hydroformylation/ cobalt catalyst/ liquid/liquid biphase catalysis分类
化学化工引用本文复制引用
吴丹,张建伟,蒋景阳..钴催化剂催化高碳烯烃氢甲酰化反应的研究进展[J].石油化工,2011,40(12):1370-1374,5.基金项目
教育部博士点基金项目(20070141046) （20070141046）
辽宁省教育厅优秀人才支持计划项目(辽教发[2006]124号). （辽教发[2006]124号）
