石油实验地质2011，Vol.33Issue(6)：645-651,656,8.
基于反相柱系统分析的原油烃类化合物全二维色—质谱图特征
Comprehensive two dimensional gas chromatography and time-of-flight mass spectrometry of hydrocarbon in crude oil: application of inverse column set
摘要
Abstract
Petroleum hydrocarbons, which span a wide range of boiling point and polarity, are very complicated. The comprehensive two dimensional gas chromatography and time-of-flight mass spec-trometry is one of the most effective methods to separate complex mixtures. An inverse column set was used to analyze petroleum hydrocarbons, and to distinguish some critical compounds, providing data for the comprehensive two dimensional gas chromatography and time-of-flight mass spectrometry of hydrocarbons in crude oil. It was concluded that, the inverse column set worked perfectly in separating two dimensionally the saturated hydrocarbons, especially isoalkane and cyclane with low molecular weight. It could be used to distinguish the UCMs (unresolved complex mixtures) from saturated hydrocarbons of biodegradation oil.关键词
反相柱系统/全二维气相色谱—飞行时间质谱/谱图识别/烃类化合物/原油Key words
inverse column set/ comprehensive two dimensional gas chromatography and time-of-flight mass spectrometry/ chromatography and mass spectrometry study/ hydrocarbon compound/ crude oil分类
能源科技引用本文复制引用
李水福,胡守志,曹剑,何生,马军,王绪龙,张冬梅,陈昱瑶..基于反相柱系统分析的原油烃类化合物全二维色—质谱图特征[J].石油实验地质,2011,33(6):645-651,656,8.基金项目
中国地质大学(武汉)构造与油气资源教育部重点实验室开放研究基金重点资助项目(TPR-2010-14,TPR-2010-11). （武汉）
