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快速凝固Fe62.1Sn27.9Si10合金的分层组织和偏晶胞形成机理

李志强 王伟丽 翟薇 魏炳波

物理学报2011,Vol.60Issue(10):705-714,10.
物理学报2011,Vol.60Issue(10):705-714,10.

快速凝固Fe62.1Sn27.9Si10合金的分层组织和偏晶胞形成机理

Formation mechanism of layered microstructure and monotectic cell within rapidly solidified Fe62.1Sn27.9Si10 alloy

李志强 1王伟丽 1翟薇 1魏炳波1

作者信息

  • 1. 西北工业大学应用物理系,西安710072
  • 折叠

摘要

Abstract

Ternary Fe62.1Sn27.9Si10 monotectic alloy is rapidly solidified in drop tube with the freely-falling-body techniqual and with melt spinning method separately.The phase separation,the microstructure characteristics,and the heat transfer of this alloy are investigated theoretically.Under free fall condition,the core-shell structure with two layers is formed because of Marangoni migration and surface segregation,where the Sn-rich phase is always located at droplet surface and the Fe-rich phase in the center.With the decrease of droplet diameter,both cooling rate and temperature gradient increase quickly,which facilitates the rapid growth of monotectic cell.With the increase of wheel speed,the cooling rate of alloy ribbon increases from 1.1×107 to 6.5×107 K/s,the fluid flow and the phase separation are suppressed to a great extent,and the "nine layers → two layers → no layer" structural transition occurs during the rapid solidification of Fe62.1Sn27.9Si10 alloy obtained by the melt spinning method.Meanwhile,the FeSn+L2→FeSn2 peritectic transformation is also suppressed,thus resulting in different phase constitutions as compared with the case of free fall condition.The energy dispersive spectroscopy(EDS) analysis reveals that the αFe phase exhibits a conspicuous solute trapping effect during rapid solidification.

关键词

Fe-Sn-Si偏晶合金/相分离/快速凝固/溶质截留

Key words

Fe-Sn-Si monotectic alloy/phase separation/rapid solidification/solute trapping

分类

矿业与冶金

引用本文复制引用

李志强,王伟丽,翟薇,魏炳波..快速凝固Fe62.1Sn27.9Si10合金的分层组织和偏晶胞形成机理[J].物理学报,2011,60(10):705-714,10.

基金项目

国家自然科学基金 ()

西北工业大学基础研究基金(批准号:JC201050)资助的课题 ()

物理学报

OA北大核心CSCDCSTPCDSCI

1000-3290

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