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银纳米颗粒对四苯基卟啉Q带荧光寿命的延长

杨振岭 刘玉强 杨延强

物理学报2012,Vol.61Issue(3):469-473,5.
物理学报2012,Vol.61Issue(3):469-473,5.

银纳米颗粒对四苯基卟啉Q带荧光寿命的延长

Extended Q-band fluorescence lifetime of tetraphenyl porphyrins adsorbed on silver nanoparticles

杨振岭 1刘玉强 1杨延强1

作者信息

  • 1. 哈尔滨工业大学物理系凝聚态科学与技术研究中心,哈尔滨150001
  • 折叠

摘要

Abstract

The change of Q-band fluorescence lifetime of tetraphenyl porphyrins(TPP) adsorbed on the surface of silver nanoparticles is reported.The lifetime is extended when the surface plasmon resonant peak of silver nanoparticles is adjusted to be resonant with the Q- absorption band,which is due to the fact that silver nanoparticles bring a large surface plasmon resonant enhancement effect to the surface light field,and the excited TPP molecules have a higher polarity.The enhanced light field will stabilize the TPP molecules of high polarity,which causes the extended Q-band fluorescence lifetime.It has an important significance in photodynamic therapy using porphyrins as photosensitizer.

关键词

银纳米颗粒/表面等离激元共振/四苯基卟啉/Q带荧光

Key words

silver nanoparticles/surface plasmon resonant/tetraphenyl porphyrin/Q-band fluorescence

分类

化学化工

引用本文复制引用

杨振岭,刘玉强,杨延强..银纳米颗粒对四苯基卟啉Q带荧光寿命的延长[J].物理学报,2012,61(3):469-473,5.

基金项目

国家自然科学基金 ()

国防基础科研项目 ()

总装备部预研基金 ()

冲击波物理与爆轰物理国防科技重点实验室基金(批准号:2011-2)资助的课题 ()

物理学报

OA北大核心CSCDCSTPCDSCI

1000-3290

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