新型炭材料2011，Vol.26Issue(5)：335-340,6.DOI:10.1016/S1872-5805(11)60085-1
膨胀石墨基镍/炭复合物
Nickel/Carbon composite materials based on expanded graphite
摘要
Abstract
Monolithic nickel/carbon(Ni/C)composites were prepared from coal tar pitch-impregnated compressed expanded graphite pre-decorated with NiO particles(EGNiO)by pyrolysis at 550 ℃ and subsequent steam activation at 800 ℃.The microstructural arrangement of the Ni-comprising nanoparticles in the composites was investigated using transmission electron microscopy.The specific surface area and porosity of the composites were analyzed by nitrogen adsorption.The catalytic activity of the composites was compared with the material obtained by the conventional H2 treatment of EGNiO using hydrocracking of 2,2,3-trimethylpentane as a model reaction.关键词
膨胀石墨/锈/炭复合物/微结构/催化活性Key words
Expanded graphite/Ni/C composites/Microstructure/Catalytic activity分类
通用工业技术引用本文复制引用
I.M.Afanasov,O.I.Lebedev,B.A.Kolozhvary,A.V.Smirnov,G.Van Tendeloo..膨胀石墨基镍/炭复合物[J].新型炭材料,2011,26(5):335-340,6.基金项目
The authors are indebted to Dr.V.A.Morozov (Chemistry Department,Moscow State University)for the consultations on XRD,Dr.O.N.Shomikova for the conducting surface area measurements,and D.A.Kirilenko(EMAT,University of Antwerp)for the helpful discussions.Part of this work has been conducted within the Interuniversity Attraction Poles (IAP)-Ⅵ framework of the Belgian government. （Chemistry Department,Moscow State University）
