燕山大学学报2011,Vol.35Issue(6):471-475,5.DOI:10.3969/j.issn.1007-791X.2011.06.001
新型三维(3,3)碳纳米管聚合体
New three-dimensional (3, 3) carbon nanotubepolymers
摘要
Abstract
The phase transition of single-walled (3, 3) carbon nanotube bundle under pressure is studied. At a hydrostatic pressure of 40 Gpa, (3, 3) carbon nanotube bundles are directly polymerized to form a new hexagonal tree-dimensional carbon nanotube polymer (called hexagonal 3D- (3, 3) carbon). Unloading the pressure, the hexagonal 3D- (3, 3) carbon is quenchable at ambient pressure, showing semiconducting and superhard properties. The current study gives a theoretical support for compressing carbon nanotubes to obtain new carbon allotropes.关键词
纳米管/高压/超硬/新型三维碳纳米管聚合体Key words
nanotube/ high pressure/ superhard/ new three-dimensional carbon nanotube polymer分类
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何巨龙,赵智胜,田永君..新型三维(3,3)碳纳米管聚合体[J].燕山大学学报,2011,35(6):471-475,5.基金项目
国家自然科学基金资助项目(50821001,51072176,91022029) (50821001,51072176,91022029)
全国高等学校优秀博士学位论文作者专项基金资助项目(2007B36) (2007B36)
燕山大学优秀博士生科学基金(YSUSF201101) (YSUSF201101)