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胜利褐煤的加压热解特性分析

许凯 胡松 向军 孙路石 卢腾飞 帅超

中国电机工程学报2011,Vol.31Issue(29):15-20,6.
中国电机工程学报2011,Vol.31Issue(29):15-20,6.

胜利褐煤的加压热解特性分析

Analysis on the Behavior of Pressurized Pyrolysis of Shengli Lignite

许凯 1胡松 1向军 1孙路石 1卢腾飞 1帅超1

作者信息

  • 1. 煤燃烧国家重点实验室(华中科技大学),湖北省武汉市430074
  • 折叠

摘要

Abstract

In order to investigate the influence of pressure on the behavior of coal pyrolysis, the pressurized pyrolysis of Shengli lignite was carried out under high temperature pressurized thermogravimetric analyzer (PTGA) and the gas product released from the PTGA was detected online by the portable infrared gas analyzer, then the kinetic parameters were also calculated. Results show that coal pyrolysis under different pressure can be divided into three phases, with the increase of pyrolysis pressure, weight loss peak at the low-temperature phase shifts to higher temperature while that of the mid-temperature phase shifts to lower temperature, and the coal char yield is enhanced gradually, what's more, the yield of CO is improved and there is no obvious rule in CH4 release; the pyrolysis activation energy under different pressure is almost the same and has good kinetic compensation effect with the pre-exponential factor, the correlation coefficient is 0.982.

关键词

加压热解/气体产物/动力学参数/失重峰/补偿/效应

Key words

pressurized pyrolysis/gas product/kinetic parameter/weight loss peak/compensation effect

分类

信息技术与安全科学

引用本文复制引用

许凯,胡松,向军,孙路石,卢腾飞,帅超..胜利褐煤的加压热解特性分析[J].中国电机工程学报,2011,31(29):15-20,6.

基金项目

国家自然科学基金项目(50976043,50976038) ()

国家重点基础研究发展计划项目(973项目)(2010CB227003). ()

中国电机工程学报

OA北大核心CSCDCSTPCD

0258-8013

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