中国电机工程学报2011，Vol.31Issue(35)：78-83,6.
DBU-GAC型CO2吸附剂性能研究
Performance Research on CO2 Adsorbent of DBU-GAC
摘要
Abstract
The performance of 1,8-diazabicyclo [5,4,0]undec-7-ene （DBU） loaded on granular activated carbon （GAC） was preliminary researched to realize CO2 capture in flue gas with low cost and high efficiency. The higher the DBU load rate, its surface area, total pore volume and pore volume become smaller while the average pore size is negatively correlated to DBU load rate. The model obtained that the best of goodness of fit about the DBU adsorption on GAC is the Langmuir model, and the mono-molecular layer adsorption of DBU on GAC is greater than the multi-molecular layer adsorption. DBU-GAC adsorbent has a good thermal stability below 140~C, and DBU can effectively keep the water on the adsorbent from evaporating which is benefit to the reaction of DBU, H20, and CO2. The DBU solution performs high absorption efficiency to CO2, and its absorption capacity is about 2.6-3.3 times to monoethanolamine-methyldiethano- lamine （MEA-MDEA） solution. DBU-GAC adsorbent with an appropriate DBU load rate has a good effect on the adsorption of CO2 in simulated flue gas, and the film sealing effect of DBU on GAC must be eliminated to improve the adsorption capacity of adsorbent关键词
1,8-二氮杂二环[5/4/0]十一碳-7-烯/颗粒活性炭/吸附剂/性能/CO2Key words
1,8-diazabicyclo[5,4,0]undec-7-ene （DBU）/granular activated carbon （GAC）/adsorbent/performance/CO2分类
能源科技引用本文复制引用
周宏仓,肖旭,何都良,Nana Agyemang Prempeh,章文斌,谢文杰,徐露..DBU-GAC型CO2吸附剂性能研究[J].中国电机工程学报,2011,31(35):78-83,6.基金项目
国家自然科学基金项目（51076068) （）
江苏省自然科学基金（BK2010569) （）
江苏省高校自然科学基金项目（10KJB610007) （）
江苏省科技支撑计划（工业)项目（BE20090165) （）
江苏省“青蓝工程”中青年学术带头人项目 （）
江苏高校优势学科建设工程资助项目. （）
