中国塑料2011，Vol.25Issue(12)：31-34,4.
马来酸酐官能化ASA对PA6的增韧研究
Toughening of PA6 with MAH Functionalized Acrylate- styrene-acrylonitrile Copolymer
摘要
Abstract
Maleic anhydride （MAH） functionalized acrylate-styrene-acrylonitrile （ASA） copolymers （ASA-g-MAH） were prepared via an emulsion polymerization, and were used to toughen polyamide6（PA6）. Molau tests showed that some reactions between PA6 and ASA-g-MAH had taken place. The effect of MAH content on mechanical properties of PA6/ASA-g-MAH blends were studied. The mechanical properties of PA6/ASA-g-MAH blends increased with increasing MAH content. When MAH content was 4 ~//00, notched impact strength of the blend reached 1008 J/m. Compared with the PA6/ASA blends, the PAf/ASA-g-MAH blends had higher tensile strength and elongation at break. Scanning electron microscopy （SEM） showed ASA particles dispersed in the PA6 matrix uniformly when MAH content was 4 %. The cavitation of rubber particles and shear yielding of the PA6 matrix were the major toughening mechanisms.关键词
聚酰胺/马来酸酐/接枝共聚物/力学性能/增韧Key words
polyamide/maleic anhydride/grafting copolymer/mechanical property/toughening分类
化学化工引用本文复制引用
邓云娇,刘振国,孙树林,杨海东,张会轩..马来酸酐官能化ASA对PA6的增韧研究[J].中国塑料,2011,25(12):31-34,4.基金项目
国家自然科学基金项目（50803007) （）
吉林省科技发展计划项目（20090142) （）
