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高密度聚乙烯的过氧化物交联行为及结晶行为研究

谭志勇 阙盼 李丹 刘庆辉

中国塑料2011,Vol.25Issue(12):35-38,4.
中国塑料2011,Vol.25Issue(12):35-38,4.

高密度聚乙烯的过氧化物交联行为及结晶行为研究

Study on Cross-linking Behavior and Crystallization Behavior of Dicumyl Peroxide Crosslinked High-density Polyethylene

谭志勇 1阙盼 2李丹 1刘庆辉1

作者信息

  • 1. 长春工业大学教育部合成树脂与特种纤维工程研究中心,吉林长春130012
  • 2. 长春工业大学化学工程学院,吉林长春130012
  • 折叠

摘要

Abstract

.In this paper, the effect of dicumyl peroxide (DCP) content on cross-linking behavior of high density polyethylene (PE-HD) was investigated. The gel fraction of PE-HD increased with increasing DCP content and reached 73. 9 % with a DCP content of 3.0 %, a temperature of 170 ℃, and a reaction time of 30 min. The effect of DCP content on crystallization behavior of PE-HD was studied using differential scanning calorimetry (DSC) and X-ray diffraction (XRD). It showed that with increasing DCP content, the melting point and crystallization temperature decreased, the crystallinity degree and grain size decreased, however, the crystal structure was not affected.

关键词

高密度聚乙烯/过氧化二异丙苯/凝胶含量/结晶行为/交联

Key words

high density polyethylene/dieumyl peroxide/gel fraction/crystallization behavior/cross-linking

分类

化学化工

引用本文复制引用

谭志勇,阙盼,李丹,刘庆辉..高密度聚乙烯的过氧化物交联行为及结晶行为研究[J].中国塑料,2011,25(12):35-38,4.

基金项目

吉林省科技厅资助项目(20076024) ()

中国塑料

OA北大核心CSCDCSTPCD

1001-9278

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