质谱学报2011，Vol.32Issue(6)：350-354,366,6.
凝胶渗透色谱净化-气相色谱-质谱法测定水产品中的溴酚类化合物
Determination of Bromophenols in Fishery Product by GPC and GC/MS
摘要
Abstract
A method for the analysis of bromophenols in fishery product was developed. The sample was acidified to make sure that all of the bromophenol compounds were converted to molecular status. The molecular bromophenol was extracted by n-hexane-ethylether, purified by GPC, acetylize by acetic anhydride, and then extracted by w-hexane and determined by GC/MS. The result indicated that all of the bromophenol compounds were finely separated on the DB-17ms column with good chromatographic peak, and the derivatization with acetic anhydride was enhanced the signal sensitivity by almost a hundred times. The detection limit is 0. 3-0. 5 μg/kg, with recoveries of 70. 2%-102% and relative standard devia-tions of 5. 3%-10. 3%. The proposed method is applied to the analysis of bromophenol in fishery product, and it is found that the bromophenol contents are between 0. 3 μg/kg and 5. 0 μg/kg, among which 2,4,6-TBP has the highest level.关键词
凝胶色谱净化/水产品/溴酚类化合物/气相色谱-质谱Key words
GPC/ fishery product/bromophenols/ GC/MS分类
化学化工引用本文复制引用
徐英江,张世娟,宫向红,刘慧慧,邓旭修,张华威,张秀珍..凝胶渗透色谱净化-气相色谱-质谱法测定水产品中的溴酚类化合物[J].质谱学报,2011,32(6):350-354,366,6.基金项目
海洋公益性行业科研专项经费资助项目(200805031),海洋公益性行业科研专项经费资助项目(201105013),山东省水生动物营养与饲料泰山学者岗位资助项目 （200805031）
