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离子强度、pH和HA对Eu(Ⅲ)在北山除碳酸盐土壤上吸附的影响

刘昇平 范桥辉 潘多强 王文华 李平 吴王锁

核化学与放射化学2012,Vol.34Issue(1):46-50,5.
核化学与放射化学2012,Vol.34Issue(1):46-50,5.

离子强度、pH和HA对Eu(Ⅲ)在北山除碳酸盐土壤上吸附的影响

Effects of Ionic Strength, pH and HA on the Sorption of Eu ( Ⅲ ) Onto Beishan Decarbonated Soil

刘昇平 1范桥辉 1潘多强 1王文华 1李平 1吴王锁1

作者信息

  • 1. 兰州大学放射化学研究所,甘肃兰州 730000
  • 折叠

摘要

Abstract

The sorption of Eu(III) on Beishan decarbonated soil as a function of pH value, solid-to-liquid ratio, humic acid (HA) and ionic strength was studied using batch technique. The results indicate that Eu (III) sorption to soil is strongly dependent on pH and ionic strength, indicating that the outer-sphere complexation and ion exchange may be predominant at low pH; whereas, at high pH range, inner-sphere complexation and/or surface precipitation are prevailing. HA certainly provokes Eu (III) sorption to soil under low pH range, but significantly reduces Eu (III) sorption at high pH because of the dissolvable humate complexes in aqueous solution.

关键词

北山土壤/Eu(Ⅲ)/吸附/HA

Key words

Beishan soil/Eu(III)/sorption/humic acid

分类

化学化工

引用本文复制引用

刘昇平,范桥辉,潘多强,王文华,李平,吴王锁..离子强度、pH和HA对Eu(Ⅲ)在北山除碳酸盐土壤上吸附的影响[J].核化学与放射化学,2012,34(1):46-50,5.

基金项目

国家自然科学人才培养基金资助项目(J1030932) (J1030932)

国家自然科学基金资助项目(20871062) (20871062)

核化学与放射化学

OA北大核心CSCDCSTPCD

0253-9950

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