矿产综合利用Issue(1)：61-63,49,4.
白云鄂博氟碳铈矿-独居石混合精矿中非稀土元素的氯化反应
Carbochlorination of Non- rare Earth Elements in Baiyunebo Mixed Bastnaesite- monazite Concentrate
摘要
Abstract
The isothermal carbochlorination reaction of non-rare earth element in Baiyunebo mixed bastnaesite-mon azite concentrate and the change of its physical states in this process were investigated. When the temperature is 500t ,the non-rare earth elements of Ca,Ba and Mg in Baiyunebo mixed bastnaesite-monazite were carbochlorinat ed completely using carbon as reductant,chlorine as chlorination agent,SiCl4 as defluoration agent. Their carbon chloration products were dissolved in water with the carbonchloration products of rare-earth. TiCl4 mainly exit in the insoluble residues, less than 1 % of which was vaporized in the carbochlorination process and deposited in the recep tors around 450^. FeCl3 was deposited in the receptors at 300t to 150T!. POC13 was deposited in the receptors below 150t. The separation of Fe, P Th from other substances and the separation of a little substance which was not carbonchlorated from carbonchloration products can be realized by dissolved the carbonchloration products in water.关键词
氟碳铈矿-独居石混合精矿/非稀土元素/加碳氯化/沉积Key words
Mixed bastnaesite-monazite concentrate/ Non-rare earth element/ Carbochlorination/ Deposit分类
化学化工引用本文复制引用
张丽清,赵玲燕,周华锋,于秀兰..白云鄂博氟碳铈矿-独居石混合精矿中非稀土元素的氯化反应[J].矿产综合利用,2012,(1):61-63,49,4.基金项目
国家自然科学基金资助项目(59874008)和辽宁省高校重点实验室资助项目(LS2010122). （59874008）
