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含硫物质在栲胶脱硫过程中的氧化转化

董跃 张卫帅 凌开成 申峻

煤炭转化2012,Vol.35Issue(1):28-32,5.
煤炭转化2012,Vol.35Issue(1):28-32,5.

含硫物质在栲胶脱硫过程中的氧化转化

STUDY ON TANNIN EXTRACT DESULFURIZATION REACTION USING CYCLIC VOLTAMMETRY METHOD

董跃 1张卫帅 1凌开成 1申峻2

作者信息

  • 1. 太原理工大学环境科学与工程学院,030024 太原
  • 2. 太原理工大学化学化工学院,030024太原
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摘要

Abstract

Reaction H2S absorption solution and pentavalent vanadium, tannic extract with oxidization state (Teos) was investgated using cyclic voltammetry method. The results show that H2S is absorbed to produce bisulfide ion HS- and polysufide ion S2x- then these sufur containing substances will be oxidized by pentavalent vanadium and Teos. The reaction can be di vided into initial rapid reaction stage and slow reaction stage. For different reactions, reaction rate of sufur-containing substance and pentavalent vanadium is faster than that of sufur-contai ning substance and Teos. Additionally, Teos contributes to the formation of S26- , and pentava lent vanadium can promote to the transformation from sulfur containing substance to elemental sulfur.

关键词

栲胶脱硫/含硫物质/氧化转化

Key words

tannin extract desulfurization/ sulfur containing ion/ oxidizing transformation reaction

分类

化学化工

引用本文复制引用

董跃,张卫帅,凌开成,申峻..含硫物质在栲胶脱硫过程中的氧化转化[J].煤炭转化,2012,35(1):28-32,5.

基金项目

山西省科技攻关项目(2007032039)和山西省归国留学人员基金资助项目(2008-27). (2007032039)

煤炭转化

OA北大核心CSCDCSTPCD

1004-4248

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