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空气退火对ZnS薄膜结构和光学特性的影响

于威 高卫 吴艳华 滕晓云 傅广生

人工晶体学报2012,Vol.41Issue(1):59-63,5.
人工晶体学报2012,Vol.41Issue(1):59-63,5.

空气退火对ZnS薄膜结构和光学特性的影响

Influence of Annealing in Air on the Structure and Optical Properties of ZnS Films

于威 1高卫 1吴艳华 1滕晓云 1傅广生1

作者信息

  • 1. 河北大学物理科学与技术学院,保定 071002
  • 折叠

摘要

Abstract

The effects of annealing in air on the structure and optical properties of ZnS films were characterized by X-ray diffraction, scanning electron microscopy and photoluminescence, etc. The results indicate that the crystalline quality of the films annealed below 500℃ was improved and they still have cubic structure. While the annealing temperature was up to 550℃, the hexagonal structure of ZnO appeared in the film. Due to the oxygen in the atmosphere doped into the films, the ZnS-ZnO composite layer appeared. As the annealing temperature increasing, the size of the film grain and the transmittance increased with the energy band gap gradually approaching to that of ZnO. The superposition of the green emissions ascribed to both ZnS and ZnO in composite layer was substituted for the green emission between the energy level of defects of ZnS.

关键词

ZnS薄膜/退火/光致发光

Key words

ZnS film/annealing/photoluminescence

分类

数理科学

引用本文复制引用

于威,高卫,吴艳华,滕晓云,傅广生..空气退火对ZnS薄膜结构和光学特性的影响[J].人工晶体学报,2012,41(1):59-63,5.

基金项目

河北省自然科学基金(E2006001006)资助项目 (E2006001006)

河北大学自然科学基金(2008127)资助项目 (2008127)

河北省博士后基金资助项目 ()

人工晶体学报

OA北大核心CSCDCSTPCD

1000-985X

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