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生物油储存稳定性实验研究

张伟 赵增立 郑安庆 常胜 李海滨

燃料化学学报2012,Vol.40Issue(2):184-189,6.
燃料化学学报2012,Vol.40Issue(2):184-189,6.

生物油储存稳定性实验研究

Characterization and storage stability analysis of bio-oil

张伟 1赵增立 2郑安庆 1常胜 1李海滨1

作者信息

  • 1. 中国科学院广州能源研究所中国科学院可再生能源与天然气水合物重点实验室,广东广州510640
  • 2. 中国科学院研究生院,北京100049
  • 折叠

摘要

Abstract

A storage stability test was conducted on the bio-oil produced by fast pyrolysis of pine and corncob. The viscosity, water content and solids content of bio-oil increased after storage. However, there were no significant changes in the pH value, heating value and density of bio-oil. The quantitative analysis by GC/MS showed that the content of 1-hydroxy-2-propanone, acetic acid, and furfural were significant decreased. The content of 2-methoxy phenol, 4-methyl-2-methoxy-phenol, and 4-methyl-phenol increased. 13C NMR spectral analysis showed that the alkyl carbon and di-O-alkyl carbon content of bio-oil decreased after storage, while the content of aromatic and unsaturated carbon increased. Therefore, the aromaticity of bio-oil increased.

关键词

生物油/储存稳定性/气质联用/核磁共振

Key words

bio-oil/ storage stability/ GC/MS/ 13C NMR

分类

能源科技

引用本文复制引用

张伟,赵增立,郑安庆,常胜,李海滨..生物油储存稳定性实验研究[J].燃料化学学报,2012,40(2):184-189,6.

基金项目

国家高技术研究发展计划(863计划,2007AA05Z456). (863计划,2007AA05Z456)

燃料化学学报

OA北大核心CSCDCSTPCD

2097-213X

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