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成核剂对聚乳酸结晶行为及热性能的影响

邹俊 何伟 张竞 马腾 吴建

塑料科技2012,Vol.40Issue(2):67-71,5.
塑料科技2012,Vol.40Issue(2):67-71,5.

成核剂对聚乳酸结晶行为及热性能的影响

Effects of Nucleation Agent on Crystallization and Thermal Properties of PLA

邹俊 1何伟 1张竞 1马腾 1吴建1

作者信息

  • 1. 江苏科技大学材料科学与工程学院,江苏 镇江 212003
  • 折叠

摘要

Abstract

PLA/nucleation agent composites were prepared by melt-blending. The effects of nucleation agent on the crystallization and thermal properties of PLA were investigated by the optical polarimetry tester, polarized optical microscopy (POM), differential scanning calorimetry (DSC), X-ray diffraction (XRD) and heat deflection temperature tester. The results indicate that: TMC is an effective nucleating agent for PLA. The overall crystallization rate and crystallinity of PLA/TMC are higher than those of PLA/Talc. PLA/TMC exhibites the diffraction peaks which can be ascribed to the crystal structure of PLA. All the samples are annealed at 120 °c for 2 min, compared to neat PLA and PLA/Talc, the HDT values of PLA/TMC is about 105.6℃ .

关键词

聚乳酸/成核剂/等温结晶/耐热性

Key words

Poly(lactic acid)/ Nucleation agent/ Isothermal crystallization/ Heat resistance

分类

化学化工

引用本文复制引用

邹俊,何伟,张竞,马腾,吴建..成核剂对聚乳酸结晶行为及热性能的影响[J].塑料科技,2012,40(2):67-71,5.

基金项目

江苏省科技支撑计划(工业)项目(BE2010176) (工业)

塑料科技

OA北大核心CSTPCD

1005-3360

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