天然气化工2012，Vol.37Issue(1)：36-39,44,5.
二乙烯苯基共聚物的合成、表征和二氧化碳吸附性能
Synthesis, characterization and CO2 adsorptive properties of divinyl benzene copolymers
苑慧敏 1张永军 1王凤荣 1肖丰收 2张志翔1
作者信息
- 1. 中国石油大庆化工研究中心,黑龙江大庆163714
- 2. 浙江大学化学系催化研究所、浙江省应用化学重点实验室,杭州310007
- 折叠
摘要
Abstract
Mesoporous polymer adsorption materials were synthesized by solvent-thermal method and characterized by SEM, BET and IR. The effect of polymerization conditions and operating parameters for synthesis of the polymers on CO2 adsorptive properties of the polymer adsorption materials was investigated experimentally. The results indicated that poly (divinyl benzene) ammoniation product(Ⅰ), poly(divinyl benzene-co-4-vynyl pyridine) (Ⅱ) and poly (divinyl benzene-co-1-vynyl-imidazole) (Ⅲ) were mesoporous materials with the specific surface areas of 200 m2/g -800m2/g and the pore sizes of 20 nm-50nm, and the CO2 adsorptive capacity was in the order of Ⅲ>Ⅰ>Ⅱ.关键词
吸附/二氧化碳/介孔聚合物/二乙烯苯/1-乙烯咪唑/共聚物Key words
adsorption/carbon dioxide/mesoporous polymer/divinyl benzene/1-vynyl-imidazole/copolymer分类
化学化工引用本文复制引用
苑慧敏,张永军,王凤荣,肖丰收,张志翔..二乙烯苯基共聚物的合成、表征和二氧化碳吸附性能[J].天然气化工,2012,37(1):36-39,44,5.
