物理化学学报2012，Vol.28Issue(2)：399-406,8.DOI:10.3866/PKU.WHXB201112142
Steric Effect of Alkyl Substituted Piperidin-4-one Oximes for Corrosion Control of Mild Steel in H2SO4Medium
Steric Effect of Alkyl Substituted Piperidin-4-one Oximes for Corrosion Control of Mild Steel in H2SO4 Medium
SENTHILKUMAR Annamalai 1THARINI Kumaravel 1SETHURAMAN Mathur Gopalakrishnan1
作者信息
摘要
Abstract
Three synthesized piperidin-4-one oximes,3-ethyl-2,6-diphenyl-piperidin-4-one oxime (A),1-methyl-3-isopropyl-2,6-diphenyl-piperidin-4-one oxime (B),and 3-isopropyl-2,6-diphenyl-piperidin-4-one oxime (C),were tested at different concentrations to determine their ability to inhibit corrosion of mild steel in 1 mol · L-1 H2SO4 and measured by a mass loss method (at various temperatures),polarization and impedance measurements,X-ray diffraction (XRD),scanning electron microscopy (SEM) with energydispersive X-ray spectroscopy (EDS),and a quantum chemical method.The synergistic influence of compounds A,B and C with iodides has also been evaluated.All three compounds show good inhibition efficiency in the following order:A＞B＞C.Compounds A,B and C were found to physically adsorb on the surface of mild steel while obeying the Temkin isotherm.Polarization measurements indicated that these compounds behave as a mixed mode inhibitor.XRD and SEM with EDS studies revealed the formation of a protective barrier on the mild steel surface by these oximes.The electron donating ability of the studied molecules was tested using semi empirical methods.The studies revealed that the oxime nitrogen,the piperidine moiety,and the phenyl ring assist largely in corrosion control.The studies also showed that the steric crowding by the alkyl group in the piperidine ring affects the inhibitor efficiency.Further,it is interesting to note that all of the studied compounds exhibit synergism with iodide ions.关键词
Oxime/Steric crowding/Polarisation/Impedance/X-ray diffraction/Scanning electron microscopyKey words
Oxime/Steric crowding/Polarisation/Impedance/X-ray diffraction/Scanning electron microscopy引用本文复制引用
SENTHILKUMAR Annamalai,THARINI Kumaravel,SETHURAMAN Mathur Gopalakrishnan..Steric Effect of Alkyl Substituted Piperidin-4-one Oximes for Corrosion Control of Mild Steel in H2SO4Medium[J].物理化学学报,2012,28(2):399-406,8.
