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不同链长二元混合自组装薄膜的制备及其微观摩擦性能研究

刘蕾 宋仕永 张平余

物理化学学报2012,Vol.28Issue(2):427-432,6.
物理化学学报2012,Vol.28Issue(2):427-432,6.DOI:10.3866/PKU.WHXB201111213

不同链长二元混合自组装薄膜的制备及其微观摩擦性能研究

Preparation and Micro-Tribological Study on Dually Mixed Self-Assembled Monolayers

刘蕾 1宋仕永 1张平余2

作者信息

  • 1. 河南大学药学院,药物研究所,河南开封475004
  • 2. 河南大学,特种功能材料教育部重点实验室,河南开封475004
  • 折叠

摘要

Abstract

A series of dually mixed self-assembled monolayers were prepared by a simple step-by-step method. Four carbonyl chlorides with different chain lengths were selected and assembled onto a A/-[3-(trimethoxylsilyl)propyl] ethylene diamine self-assembled monolayer. Different mixed films were obtained by controlling the ratio of co-deposited carbonyl chlorides. The structures of the films were characterized by measuring their contact angles, ellipsometric thickness, and atomic force microscopy. No phase separation was observed in the mixed films. Micro-tribological studies were also carried out on the films. It was found that frictional coefficients decreased as the ratio of the longer component was increased.

关键词

自组装薄膜/微观摩擦力/混合薄膜/接触角/椭圆偏光厚度/原子力显微镜

Key words

Self-assembled monolayer/Micro-tribology/ Mixed film/Contact angle/Ehipsometirc thickness/ Atomic force microscopy

分类

化学化工

引用本文复制引用

刘蕾,宋仕永,张平余..不同链长二元混合自组装薄膜的制备及其微观摩擦性能研究[J].物理化学学报,2012,28(2):427-432,6.

基金项目

国家自然科学基金(51005057)资助项目 (51005057)

物理化学学报

OA北大核心CSCDCSTPCDSCI

1000-6818

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