物理化学学报2012，Vol.28Issue(3)：596-602,7.DOI:10.3866/PKU.WHXB201112261
氨基蒽醌衍生物的合成及其用作锂电池正极材料的电化学性能
Preparation and Electrochemical Performance of Aminoanthraquinone Derivative as Cathode Materials in Rechargeable Lithium Batteries
摘要
Abstract
Two novel organic compounds, 5-amino-2,3-dihydro-1,4-dyhydroxy anthraquinone (ADDAQ) and 5-amino-1,4-dyhydroxy anthraquinone (ADAQ), were synthesized as cathode materials for lithium batteries. The compounds were characterized by 1H nuclear magnetic resonance (1H NMR) spectroscopy, mass spectrometry (MS), elemental analysis (EA), Fourier transform infrared spectroscopy (FTIR), ultraviolet-visible (UV-Vis) spectroscopy. The electrochemical performance of the compounds was investigated by galvanostatic discharge/charge (GD/C) measurements, cyclic voltammetry (CV), and electrochemical impedance spectrum (EIS). Compared with ADDAQ, the initial discharge specific capacity and cycle performance of ADAQ were effectively improved. The initial discharge specific capacity of ADAQ was 185 mAh·g-1, after 50 cycles, the specific capacity was maintained at 93 mAh·g-1. A reason for this improvement is discussed.关键词
锂电池/5-氨基-2,3-二氢-1,4-二羟基蒽醌/5-氨基-1,4-二羟基蒽醌/有机正极材料/电化学性能Key words
Lithium battery/5-Amion-2,3-dihydro-1,4-dyhydroxy anthraquinone/5-Amino-1,4-dyhydroxy anthraquinone/Organic cathode material/Electrochemical performance分类
化学化工引用本文复制引用
赵磊,王安邦,王维坤,余仲宝,陈实,杨裕生..氨基蒽醌衍生物的合成及其用作锂电池正极材料的电化学性能[J].物理化学学报,2012,28(3):596-602,7.基金项目
国家重点基础研究发展计划项日(973X2009CB220100)资助 （973X2009CB220100）
