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氧化锌催化淀粉/乳酸接枝共聚物的制备与表征

王清岭 胡应模 边静

应用化学2012,Vol.29Issue(3):256-259,4.
应用化学2012,Vol.29Issue(3):256-259,4.DOI:10.3724/SP.J.1095.2012.00184

氧化锌催化淀粉/乳酸接枝共聚物的制备与表征

Synthesis and Characterization of Starch/Lactic Acid Graft Copolymer Catalyzed by Zinc Oxide

王清岭 1胡应模 1边静1

作者信息

  • 1. 中国地质大学(北京)材料科学与工程学院 北京100083
  • 折叠

摘要

Abstract

Starch/lactic acid graft copolymer was prepared with in-stiu graft copolymerization catalyzed by zinc oxide. The graft copolymer was characterized by FT-IR, 'H NMR, XRD and SEM. Effects of the reaction temperature, mass ratio between corn starch and lactic acid, amount of the catalyst and the reaction time on the grafting degree were studied. It was found that the highest grafting degree could reach 14. 20% with the mass ratio of corn starch to lactic acid being 5:1, and the mass fraction of the catalyst being 1.0% of the lactic acid, and the reaction was carried out at 95 °C for 11 h.

关键词

淀粉/乳酸/氧化锌/接枝共聚/接枝率

Key words

starch/ lactic acid/ zinc oxide/ graft copolymerization/ grafting degree

分类

化学化工

引用本文复制引用

王清岭,胡应模,边静..氧化锌催化淀粉/乳酸接枝共聚物的制备与表征[J].应用化学,2012,29(3):256-259,4.

基金项目

中央高校基本业务费专项资金(2011PY0171) (2011PY0171)

应用化学

OA北大核心CSCDCSTPCD

1000-0518

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