应用化学2012,Vol.29Issue(3):359-363,5.DOI:10.3724/SP.J.1095.2012.00171
添加剂在KOH溶液中对锌电极枝晶的影响
Influence of Additives on the Dendrite of Zinc Electrode in KOH Solution
摘要
Abstract
The influences of 6-nitrobenzimidazole, benzimidazole and Pb2+ on zinc dendrite in KOH solution (4 mol/L ) were investigated by means of current-time technique. The results showed that 6-nitrobenzimidazole, benzimidazole and Pb2+ could effectively inhibit the formation of zinc dendrites, and enhance the charging capacity of zinc electrode. It showed a high charging efficiency and effective inhibition to the growth of zinc dendrites when the charging was performed at a cathodic overpotential η = - 200 mV in 0. 05 g/L Pb2 + alkaline solution with the addition of 6-nitrobenzimidazole or benzimidazole.关键词
锌枝晶/pb2/硝基苯并咪唑/苯并咪唑/过电位Key words
zinc dendrite/ Pb2+/ nitrobenzimidazole/ benzimidazole/ overpotential分类
化学化工引用本文复制引用
胡莲跃,张胜涛,黄小红,谭建红,吴永英..添加剂在KOH溶液中对锌电极枝晶的影响[J].应用化学,2012,29(3):359-363,5.基金项目
重庆市自然科学基金计划项目资助(CSTC 2009BB7289) (CSTC 2009BB7289)