中南大学学报（自然科学版）2011，Vol.42Issue(12)：3923-3928,6.
Cu-磺化酞菁钴负载型活性炭的制备及其对PH3的催化氧化净化
Preparation of Cu-CoSPc modified activated carbon and its catalytic oxidation purification properties for PH3
摘要
Abstract
In order to obtain a more effective modified activated carbon for the purification of PH3, the AC4-supported Cu-CoSPc modified activated carbon was prepared. The effects of preparation conditions on the catalytic oxidation purification properties of the modified activated carbon were studied, and it was characterized by N2 adsorption-desorption(N2-BET), scanning electron microscope(SEM), energy dispersive spectrometer(EDS) and X-ray photoelectron spectroscopy(XPS). The results show that when the catalytic oxidation purification properties for PH3 reaches the maximum at Cu2+ concentration of 0.1 mol/L, dryness temperature of 110 'C and cremation temperature of 350 ℃. The purification capacity of Cu-CoSPc modified activated carbon is much higher than that of the previous Cu2+ modified activated carbon.关键词
活性炭/磺化酞菁钴(CoSPc)/PH3Key words
activated carbon/ sulfonated cobalt phthalocyanine(CoSPc)/ PH3分类
天文与地球科学引用本文复制引用
师雁,宁平,王学谦,蒋明,柏杨巍..Cu-磺化酞菁钴负载型活性炭的制备及其对PH3的催化氧化净化[J].中南大学学报（自然科学版）,2011,42(12):3923-3928,6.基金项目
国家高技术研究发展计划("863"计划)项目(2004AA649040):国家自然科学基金资助项目(50708044) （"863"计划）
