中南大学学报（自然科学版）2012，Vol.43Issue(2)：455-459,5.
聚偏氟乙烯/偏氟乙烯-三氟氯乙烯共聚物的共混相容性及结晶性
Miscibility and crystalline properties of poly(vinylidene fluoride)/poly(vinylidene fluoride-trifluorochloroethylene) blends
摘要
Abstract
The poly(vinylidene fluoride)/poly(vinylidene fluoride-chlorotrifluoro ethylene) blend membranes were prepared by a solution cast approach after physical blending. The miscibility, crystallization properties and surface morphology of the samples were investigated by differential scanning calorimetry, X-ray diffraction, Fourier transform infrared spectra and scanning electron microscopy. The results show that the random copolymer P(VDF-CTFE) in the PVDF/P(VDF-CTFE) blends has a certain miscibility with PVDF, which affects the crystal-melt thermodynamic characteristics of PVDF. In PVDF/P(VDF-CTFE) blend crystallization process, P(VDF-CTFE) is beneficial for the formation of p phase. PVDF is well distributed in the PVDF/P(VDF-CTFE) blends. The spherulite is reduced by decreasing the content of the PVDF.关键词
聚偏氟乙烯/偏氟乙烯-三氟氯乙烯共聚物/共混/相容性/结晶性Key words
poly(vinylidene fluoride)/ poly(vinylidene fluoride-trifluorochloroethylene)/ blend/ miscibility/ crystalline property分类
化学化工引用本文复制引用
李衡峰,谢玲,边宏,李俊..聚偏氟乙烯/偏氟乙烯-三氟氯乙烯共聚物的共混相容性及结晶性[J].中南大学学报（自然科学版）,2012,43(2):455-459,5.基金项目
国家自然科学基金资助项目(50703048) （50703048）
