安徽工程大学学报2012，Vol.27Issue(1)：14-16,3.
偕胺肟-Fe（Ⅲ）配合物纤维催化合成乙酸丁酯的研究
The catalytic properties for synthesis of n-Butyl acetate of amidoxime fibers supported-Fe（Ⅲ） complex
摘要
Abstract
Amidoxime Fibers Supported-Fe（Ⅲ） Complex（AOFs-Fe（Ⅲ）） was synthesized by reaction of Amidoxime fibers and Fe2（SO4）3 solution in this research.Its catalytic performance for Synthesis of n-Butyl acetate was investigated under different conditions including materials ratio、reaction time、reaction temperature and amount of catalyst,its repeated usage and regeneration capacity were researched.The result shows the optimum conditions in heating reflux are： the molar ratio of acid and alcohol was 3∶1,the reaction time was 3.0 h,the amount of catalyst was 1 g;the yield of n-Butyl acetate is 12.8 g/g（n-Butyl acetate/ AOFs-Fe（Ⅲ））;AOFs-Fe（Ⅲ） can be used repeatedly and has a regeneration capacity;AOFs-Fe（Ⅲ） is a esterification catalyst being safe as non-toxic and being prone to separation.关键词
偕胺肟-Fe（Ⅲ）配合物纤维/催化酯化/乙酸正丁酯/AOFs-Fe（Ⅲ）Key words
amidoxime fibers supported-Fe(Ⅲ) complex/catalytic performance/n-Butyl acetate/AOFs-Fe(Ⅲ)分类
化学化工引用本文复制引用
黄雅,吴之传,席敏,孙晓辉..偕胺肟-Fe（Ⅲ）配合物纤维催化合成乙酸丁酯的研究[J].安徽工程大学学报,2012,27(1):14-16,3.基金项目
安徽省高校自然科学基金资助项目 （）
