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熔盐法制备梯度型LiNixCoyMn1-x-yO2电极材料的研究

朱靖 刘永光 赵艳琴 王岭

材料工程Issue(3):8-11,4.
材料工程Issue(3):8-11,4.

熔盐法制备梯度型LiNixCoyMn1-x-yO2电极材料的研究

Study on the Concentration-gradient LiNixCoyMn1-x-yO2Electrode Material Prepared in the Molten Salt Method

朱靖 1刘永光 1赵艳琴 1王岭1

作者信息

  • 1. 河北联合大学化工学院,河北唐山063009
  • 折叠

摘要

Abstract

The layered cathode material LiNi1-x-u, CoxMnyO2 was prepared at different temperatures in the molten salt method. Experiments were carried out to test the charge and discharge properties of the material. The XRD and SEM experiments show that the prepared material has a typical a-NaFeO2 layered structure with the particles diameter range from 200nm to 400 nm. The capacity of the prepared material at 800℃is 166. 8mAh/g with a retention of 99% in the first charge-discharge cycle, tested within the voltage cut off limits of 2. 75 and 4. 5 V. Besides, the results show that the material demonstrates a good rate capability.

关键词

锂离子电池/浓度梯度型正极材料/熔盐法/倍率特性

Key words

lithium-ion batteries/concentration-gradient cathode material/molten salt method/rate capability

分类

信息技术与安全科学

引用本文复制引用

朱靖,刘永光,赵艳琴,王岭..熔盐法制备梯度型LiNixCoyMn1-x-yO2电极材料的研究[J].材料工程,2012,(3):8-11,4.

基金项目

河北省教育厅计划项目(2010288) (2010288)

唐山市科学技术研究与发展计划指导项目(09130204c) (09130204c)

材料工程

OA北大核心CSCDCSTPCD

1001-4381

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