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X射线衍射法研究天然橡胶/黏土纳米复合材料的插层过程

戈明亮 贾德民

材料工程Issue(3):43-46,51,5.
材料工程Issue(3):43-46,51,5.

X射线衍射法研究天然橡胶/黏土纳米复合材料的插层过程

Study on Intercalating Stage of Natural Rubber/Clay Nanocomposites by X-ray Diffraction

戈明亮 1贾德民2

作者信息

  • 1. 华南理工大学机械与汽车工程学院,广州510640
  • 2. 华南理工大学材料科学与工程学院,广州510640
  • 折叠

摘要

Abstract

The organic clay(Org-clay) was prepared by alkyl ammonium ions treating of Na-montmo-rillonite, and then the natural rubber(NR)/Org-clay nanocomposites were prepared by intercalation method. The structure and morphology of the nanocomposites were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM), the results show that Org-clay can disperse in the rubber matrix at nanometer size. The result of XRD indicated that natural rubber chains could be intercalated into the interlayer of the Org-clay during the mixing stage. During the vulcanizing stage, with increasing vulcanization time the basal space of Org-clay was slightly increased. At the end of rubber vulcanization process, the NR chains were fixed in the interlayer of the Org-clay because of cross-linked network structure of vulcanizate.

关键词

天然橡胶/黏土/纳米复合材料/插层过程/XRD

Key words

natural rubber/clay/nanocomposites/intercalation process/X-ray diffraction

分类

通用工业技术

引用本文复制引用

戈明亮,贾德民..X射线衍射法研究天然橡胶/黏土纳米复合材料的插层过程[J].材料工程,2012,(3):43-46,51,5.

基金项目

中国博士后科学基金(20100470911) (20100470911)

材料工程

OA北大核心CSCDCSTPCD

1001-4381

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