材料工程Issue(6)：67-70,4.
热固性树脂固化动力学模型简化的新方法
New Simplification Method of Thermosetting Resin Curing Kinetic Models
摘要
Abstract
Temperature-time-transition (TTT) diagram is a useful tool for analyzing and designing the curing process, which has an important research value. The traditional iso-conversional curves drawing process in TTT diagram is a complicated process which is time consuming and costly. The relationship of temperature, time and degree of cure is controlled by the curing kinetic equation. From the perspective of the curing kinetic equation, studying the iso-conversional curves with the numerical simulation method is a novel method which can reduce both time and cost. For two kinds of resin curing kinetics models, the resin degree of cure is simulated, and the simulation program has been verified. Based on this work, the iso-conversional curves of two kinetic models are plotted and the relationship of the temperature, time and degree of cure is discussed. The result shows that a negative linear relationship exists between the temperature and the logarithm of the time. Then by curve fitting method a relatively simple relationship of the iso-conversional curves is obtained which can be used more conveniently in engineering practice without cumbersome computation.关键词
固化动力学模型/固化度/TTT转变/数据拟合/数值模拟Key words
curing kinetic model (degree of cures TTT transitions data fitting (numerical simulation分类
通用工业技术引用本文复制引用
王晓霞,王成国,贾玉玺,罗玲..热固性树脂固化动力学模型简化的新方法[J].材料工程,2012,(6):67-70,4.基金项目
国家973计划(2010CB631102) （2010CB631102）
国家与山东省自然科学基金(50973056,51173100 （）
JQ201016) （）
山东大学自主创新基金(2009JQ013) （2009JQ013）
