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复配增塑剂对聚乙烯醇薄膜性能的影响

任德财 林鹏 钱镭 贺培凤 杜宇虹 薛蕊

材料工程Issue(6):86-90,5.
材料工程Issue(6):86-90,5.

复配增塑剂对聚乙烯醇薄膜性能的影响

Effect of Mixture of Plasticizer on Properties of PVA Films

任德财 1林鹏 2钱镭 1贺培凤 1杜宇虹 1薛蕊1

作者信息

  • 1. 黑龙江东方学院食品与环境工程学部,哈尔滨150086
  • 2. 黑龙江工程学院材料与化学工程系,哈尔滨150050
  • 折叠

摘要

Abstract

Modified Polyvinyl alcohol (PVA) films were prepared by casting from the solutions using urea/triethanolamine as a mixed plasticizer. The interactions between urea/triethanolamine and PVA were studied by FT-IR. Crystallinity and thermoplasticity of modified PVA were tested by TGA, DSC, and XRD. At the same time, mechanical properties, light transmission rate, water solubility of modified PVA also were tested. The results showed that mixture of plasticizer can decrease the extent of inter-or intramolecular hydrogen bonds in PVA, crystallinity and melting point of modified PVA depresses without bringing about any obvious impact on the thermal decomposition temperature. With the mass fraction of mixture of plasticizer increasing, the modified PVA had lower strength and higher elongation at break, good light transmission rate, lower degree of swelling and higher solubility.

关键词

聚乙烯醇/增塑剂/尿素/三乙醇胺

Key words

polyvinyl alcohol/plasticizer/urea/triethanolamine

分类

化学化工

引用本文复制引用

任德财,林鹏,钱镭,贺培凤,杜宇虹,薛蕊..复配增塑剂对聚乙烯醇薄膜性能的影响[J].材料工程,2012,(6):86-90,5.

材料工程

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