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MnOx/AC的制备及电催化氧化降解苯酚

于秀娟 高铭晶

材料科学与工程学报2011,Vol.29Issue(6):864-868,5.
材料科学与工程学报2011,Vol.29Issue(6):864-868,5.

MnOx/AC的制备及电催化氧化降解苯酚

Preparation of MnOx/AC and Electrochemical Degradation of Phenol

于秀娟 1高铭晶1

作者信息

  • 1. 黑龙江大学环境科学与工程系,黑龙江哈尔滨150080
  • 折叠

摘要

Abstract

MnOx/AC catalyst was prepared by the reduction of KMnO7 by activated carbon(AC) powder.It was characterized by scanning electron microscopy(SEM),X-ray photoelectron spectroscopy(XPS).It was shown that Mn was present in the chemical state of MnO2.And MnOx/AC electrode was obtained by pressure.An electrolytic cell with MnOx/AC cathode and Ti/RuO2 anode was used to treat phenol wastewater.Current density was the main factor among some influence factors.Approximately 99.7% of phenol was removed after electrolysis for 100 min with the optimal parameters of current density of 39mA/cm2,the electrode distance of 3cm,the initial pH value of 6.8,the electrolyte concentration of 0.1mol/L Na2SO4,the initial phenol concentration for 100mg/L.And MnOx/AC electrode had better catalytic activity in degradation of phenol.

关键词

MnOx/电催化/苯酚

Key words

MnOx/electrocatalysis/phenol

分类

化学化工

引用本文复制引用

于秀娟,高铭晶..MnOx/AC的制备及电催化氧化降解苯酚[J].材料科学与工程学报,2011,29(6):864-868,5.

材料科学与工程学报

OA北大核心CSCDCSTPCD

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