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焙烧温度对溶胶-凝胶法制备磷酸钒锂的性能

刘丽英 张海燕 张映慧

电源技术2012,Vol.36Issue(5):633-635,3.
电源技术2012,Vol.36Issue(5):633-635,3.

焙烧温度对溶胶-凝胶法制备磷酸钒锂的性能

Influences of roasting temperature on performance of lithium vanadium phosphate synthesized by sol-gel method

刘丽英 1张海燕 1张映慧1

作者信息

  • 1. 广东工业大学材料与能源学院,广东广州510006
  • 折叠

摘要

Abstract

A sol-gel method was adopted to prepare Li3V2 (PO4)3 with citric acid as chelator and C sources. The electrochemical and physical performance of the products was characterized through galvanostatic charge-discharge tests, XRD and SEM. The results show that general electrochemical properties of Li3V2 (PO4)3are influenced by roasting temperature. The materials prepared at 700 ℃ have better electrochemical properties with the first discharge specific capacity of 105.6 mAh/g and capacity retention of 99.0% after 10 cycles. As-synthesized materials have well developed crystal structure and uniform grain distribution.

关键词

溶胶-凝胶法/Li3V2(PO4)3/焙烧温度/电化学性能

Key words

sol-gel/ Li3V2(PO4)3/ roasting temperature/ electrochemical performance

分类

信息技术与安全科学

引用本文复制引用

刘丽英,张海燕,张映慧..焙烧温度对溶胶-凝胶法制备磷酸钒锂的性能[J].电源技术,2012,36(5):633-635,3.

基金项目

广东省高校优秀青年创新人才培育项目(LYM09061) (LYM09061)

电源技术

OA北大核心CSCDCSTPCD

1002-087X

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