分析化学2012，Vol.40Issue(3)：442-446,5.DOI:10.3724/SP.J.1096.2012.10715
微囊藻毒素分子印迹传感器的制备与应用
Preparation and Application of Microcystins Sensor Based on Molecular Imprinting
摘要
Abstract
A molecularly imprinted film sensor was prepared by cyclic voltammetry on a gold electrode surface using Oaminophenol as the monomer, microcystin (MC-LR) as a template, and then MC-LR was determined by amperometry. The optimum preparation conditions for the sensor were as follows: pH=4.5, monomer/template = 1.4 ×108∶1; elution time= 10 min. The characteristics of the sensor such as the linear relationship, service life, selectivity were investigated. Experimental results showed that the linear response of the sensor is 0.05-0.35 mg/L, the recovery of standard addition is 80% to 105% and the detection limit is 7.3 μg/L. In comparison with HPLC, when the confidence level was 99%, there is no systematic error. The sensor exhibited a good selectivity and sensitivity关键词
微囊藻毒素/分子印迹/电聚合/传感器Key words
Microcystins/ Molecular imprinting/ Electricity polymerization/ Sensor引用本文复制引用
申晴,崔莉凤,赵硕,李科..微囊藻毒素分子印迹传感器的制备与应用[J].分析化学,2012,40(3):442-446,5.基金项目
本文系北京市自然科学基金(No.2102015)资助项目 （No.2102015）
