高等学校化学学报2012，Vol.33Issue(3)：453-457,5.DOI:10.3969/j.issn.0251-0790.2012.03.004
一步水热合成Mn-ZSM-5纳米分子筛及其性能
Synthesis and Property of Nano-sized Mn-ZSM-5 Zeolite via One-step Hydrothermal Method
摘要
Abstract
High pure Mn-ZSM-5 zeolite was synthesized through one-step hydrothermal method by direct introduction of divalent manganese source under strong alkaline condition. The samples were characterized by XRD, FTIR, 29Si NMR, SEM, ICP and N2 adsorption-desorption techniques. The results indicated that manganese irons were incorporated into the zeolite skeleton. Using styrene oxidation as a probe reaction, H202 as the oxidant and Mn-ZSM-5 as the catalyst, the conversion of styrene reached 84. 98% , turnover number was 208, styrene epoxide selectivity and yield was about 87. 62% and 74. 46% , respectively. The synthesized nano sized Mn-ZSM-5 is a promising catalyst for oxidation reactions.关键词
Mn-ZSM-5分子筛/强碱/水热合成/苯乙烯氧化Key words
Mn-ZSM-5 zeolite/Strong alkaline/Hydrothermal synthesis/Styrene oxidation分类
化学化工引用本文复制引用
张前,裘式纶,陈春影,丁双,张文婷,许迪欧,唐晓建,王润伟,姜日花,张宗弢..一步水热合成Mn-ZSM-5纳米分子筛及其性能[J].高等学校化学学报,2012,33(3):453-457,5.基金项目
国家自然科学基金(批准号:20971052)资助. （批准号:20971052）
