高等学校化学学报2012，Vol.33Issue(6)：1205-1213,9.DOI:10.3969/j.issn.0251-0790.2012.06.015
磺酰脒基桥连的锌卟啉-富勒烯化合物构型对光诱导电子转移机理的影响
Influence of Configuration on Photoinduced Electron-transfer Mechanism in Sulfonyl Amidine Linked Porphyrin-fullerene Dyad
摘要
Abstract
A novel sulfonyl amidine linked porphyrin-fullerene dyad ZnP-H-C60 was facilely synthesized via a three components one-pot coupling reaction. There are two isomers(Z- and E-) in the dyad solution in low-polarity solvents, such as chloroform and toluene. We found that the photoinduced electron-transfer(PET) process could occur in two isomers, but the electron-transfer mechanism was different from each other. The electron transfer process was mediated by the intramolecular hydrogen-bond in ( Z-) ZnP-H-C60; and in (E-) ZnP-H-C60, the porphyrin-fullerene exciplex was the precursor of the charge separation (CS) state due to the closer distance between porphyrin and fullerene entities.关键词
卟啉/富勒烯/光诱导电子转移/氢键Key words
Porphyrin/Fullerene/Photoinduced electron-transfer/Hydrogen-bond分类
化学化工引用本文复制引用
贺林,陈晨,李飞,朱义州,郑健禺..磺酰脒基桥连的锌卟啉-富勒烯化合物构型对光诱导电子转移机理的影响[J].高等学校化学学报,2012,33(6):1205-1213,9.基金项目
国家"九七三"计划项目(批准号:2011CB932902)和国家自然科学基金(批准号:21172126,20802038)资助. （批准号:2011CB932902）
