1,10-邻菲啰啉并咪唑衍生物阴离子受体的合成及识别性能OA北大核心CSCDCSTPCD
Synthesis of Two Anion Receptors of 1H-Imidazo [4,5-f][1,10] phenanthroline Derivatives and Their Recognition Properties
设计合成了2个1,10-邻菲啰啉并咪唑衍生物阴离子受体2-(2-羟基苯基)-1H-咪唑[4,5-f][1,10]邻菲啰啉(1)和2-(2-羟基-5-溴苯基)-1H-咪唑[4,5-f][1,10]邻菲啰啉(2),受体2的结构由X射线单晶衍射分析确证.通过紫外-可见光谱滴定及1H NMR滴定研究了这2个受体对F-,CI-,Br-,I-,H2PO4-和AcO-6种阴离子的识别传感作用及作用机理.结果表明,受体对AcO-,F和H2PO4-有较强的传感作用…查看全部>>
Anion play important roles in a wide range of chemical, biological and environmental processes. So anion binding and sensing became an active research field in supramolecular chemistry with potential applications in biomedical and environmental monitoring, anion exchange as well as anion transport. Artificial neutral receptors for an ions are designed and synthesized in which color metric sensors are paid a good deal of attention for they could efficiently c…查看全部>>
陈华梅;岳凡;林海;林华宽
新疆大学化学化工学院,乌鲁木齐830046新疆大学化学化工学院,乌鲁木齐830046南开大学吸附与分离功能材料重点实验室,天津300071南开大学化学系,天津300071
化学化工
1,10-邻菲罗啉并咪唑衍生物晶体结构阴离子识别
1H-Imidazo[4,5-f] [1,10]phenanthroline derivativeCrystal structureAnion recognition
《高等学校化学学报》 2012 (6)
1239-1244,6
新疆维吾尔自治区自然科学基金(批准号:2011211B06)和新疆大学自然科学基金(批准号:BS08011)资助.
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