高等学校化学学报2012，Vol.33Issue(6)：1264-1270,7.DOI:10.3969/j.issn.0251-0790.2012.06.024
CTAB作用下纳米复合材料Ag/ZnO-SnO2的制备与光催化降解罗丹明B
Preparation of Ag/ZnO-SnO2 by CTAB-assisted and Photocatalytic Degradation of Rhodamine B
摘要
Abstract
The nano-composite Ag/ZnO-SnO2 under cetyltrimethylammonium bromide (CTAB) was prepared with a molar ratio of Ag, Zn and Sn of 0.1:2:1 by the sol-gel method combined with temperature-programmed treatment. The phase composition, structures and morphologies of the nanocomposite Ag/ZnO-SnO2 (CTAB) were characterized by X-ray diffraction(XRD), X-ray photoelectron spectroscopy(XPS), transmission electron microscopy (TEM) , N2 adsorption-desorption tests and scanning electron microscopy assisted X-ray energy dispersive spectroscopy(SEM-EDS). The results show that the nanocomposite Ag/ZnO-SnO2 is well wurtzite and rutile structures, and Ag in the nano-composite Ag/ZnO-SnO2 is metallic Ag°. Compared with no CTAB-assisted nanocomposite, the nanocomposite Ag/ZnO-SnO2 ( CTAB ) has uniformly distribution and shows regularly nano-rods. By the photocatalytic degradation of RhB, under UV and visble light irradiation, the photocatalytic activity of Ag/ZnO-SnO2 under CTAB-assisted is enhanced, of which is higher than that of Ag/ZnO-SnO2, ZnO-SnO2, ZnO and Degussa P-25.关键词
溴化十六烷基三甲基胺/溶胶-凝胶法/Ag/ZnO-SnO2/光催化/罗丹明BKey words
Cetyltrimethylammoniura bromide/Sol-gel method/Ag/ZnO-SnO2/Photocatalysis/Rhodamine B分类
化学化工引用本文复制引用
李莉,禚娜,高宇,赵月红,李恩帅,赵立杰..CTAB作用下纳米复合材料Ag/ZnO-SnO2的制备与光催化降解罗丹明B[J].高等学校化学学报,2012,33(6):1264-1270,7.基金项目
黑龙江省自然科学基金(批准号:B201200556)、黑龙江省教育厅科学技术研究项目(批准号:12511592,11541396)、黑龙江省政府博士后资助经费(批准号:LBH-Z11108)、黑龙江省研究生创新科研项目(批准号:YJSCX2011-199HLJ)和齐齐哈尔大学创新科研项目(批准号:YJSCX2010-017X)资助. （批准号:B201200556）
