高等学校化学学报2012，Vol.33Issue(6)：1344-1349,6.DOI:10.3969/j.issn.0251-0790.2012.06.037
基于小分子掺杂及聚电介质模板导向的水溶性聚苯胺的CPO酶促氧化合成及结构性能表征
Synthesis, Structure and Performance of Soluble Polyaniline by CPO-catalyzed Oxidation Using Small Molecule as Dopant or Polyelectrolyte as Template
摘要
Abstract
A green enzymatic approach for the synthesis of soluble polyaniline ( PANI) from p-phenylene diamine(PPD) monomer by chloroperoxidase ( CPO)-catalyzed H2O2-oxidation was proposed. The performance of aim product was improved compared to that of eigenstate polymer by the introduction of small molecule as dopant or polyelectrolyte as template, which was testified by UV-Vis spectra, cyclic voltammetry curve, electron microscope scanning, thermal gravimetric analysis and conductivity measurement. Sodium perchlorate was screened as the most effective dopant, and the corresponding product when n(PPD): n(NaC104)= 1 : 1 had fine layer structure and strong reversible redox capacity; The PANI obtained with polystyrene sulfonate(SPS) as the template had the best thermal stability and solubility as well as maximum conductivity. The enzymatic polymerization was analyzed according to the structure of active site in CPO.关键词
氯过氧化物酶/聚苯胺/聚电介质模板剂/结构性能Key words
Chloroperoxidase/Polyaniline/Polyelectrolyte template-oriented/Structure and performance分类
化学化工引用本文复制引用
王亚丽,聂艳艳,蒋育澄,胡满成,李淑妮,翟全国..基于小分子掺杂及聚电介质模板导向的水溶性聚苯胺的CPO酶促氧化合成及结构性能表征[J].高等学校化学学报,2012,33(6):1344-1349,6.基金项目
国家自然科学基金(批准号:21176150)和中央高校专项基金(批准号:GK201001005)资助. （批准号:21176150）
