高等学校化学学报2012，Vol.33Issue(6)：1355-1359,5.DOI:10.3969/j.issn.0251-0790.2012.06.039
超疏水导电聚苯胺的界面聚合
Superhydrophobic Conducting Polyaniline Prepared via Interfacial Polymerization
摘要
Abstract
Three-dimensional(3D) micro/nanostructures of polyaniline(PANI) were self-assembled by template-free method combined with interfacial polymerization in the presence of perlluorosebacic acid ( PFSEA) as dopant. The 3D micro/nanostructures of PANI show both electrical conductivity and superhydrophobicity. It was proposed that the aniline filled bi-layer micelles composed of PFSEA/An salt were served as the soft-templates of the self-assembled nanofibers, then those nanofibers were self-assembled to form 3D-microstructures by the intermolecular interactions including hydrogen bonding and hydrophobic interaction as the driving forces. Moreover, their morphology and size can be controlled by changing the concentration and the molar ratio of aniline and oxidant. The method is a facile approach to prepare conducting polymer 3D architectures assembled by 1D-nanostructure.关键词
导电聚苯胺/界面聚合/三维微/纳米结构/超疏水性Key words
Conducting polyaniline/Interfacial polymerization/Three-dimensional micro/nanostructure/Superhydrophobicity分类
化学化工引用本文复制引用
王亮,丁春梅,朱英,万梅香,江雷..超疏水导电聚苯胺的界面聚合[J].高等学校化学学报,2012,33(6):1355-1359,5.基金项目
国家"九七三"计划项目(批准号:2010CB934701)、国家自然科学基金(批准号:20974006)、北京市自然基金(批准号:2102027)、新世纪优秀人才支持计划(批准号:NECT-08-0030)和中央高校基本科研业务专项资金(批准号:YWF-10-01-B16)资助. （批准号:2010CB934701）
