硅酸盐学报2012，Vol.40Issue(4)：577-582,6.
Sb2O3部分替代V2O5对V2O5–P2O5–Sb2O3–Bi2O3体系玻璃电性能的影响
Effect of Sb_2O_3 Replace V_2O_5 on the Electronic Property of V2O5–P2O5–Sb2O3–Bi2O3 Glass System
李宏彦 1朱志梁 2杨凤丽 3庄卫东3
作者信息
- 1. 北京有色金属研究总院,稀土材料国家工程研究中心,有研稀土新材料股份有限公司,北京100088／京东方科技集团股份有限公司,北京100015
- 2. 北京北旭电子玻璃有限公司,北京100015
- 3. 北京有色金属研究总院,稀土材料国家工程研究中心,有研稀土新材料股份有限公司,北京100088
- 折叠
摘要
Abstract
The electronic property,structure and crystallization of V2O5–P2O5–Sb2O3–Bi2O3 glass system were investigated via vol-ume resistivity,infrared spectroscopy and X-ray diffraction,respectively.The result shows that Sb2O3 partially substitutes V2O5,leading to the increase of the volume resistivity of glasses.The characteristic of the electronic conduction surrounding V4＋ and V5＋ ions for transit was restrained substantially,and consequently the volume resistivity of the glasses with 15% Sb2O3 and 20%Sb2O3 reached a practical level.The substitution of Sb2O3 with V2O5 in vanadate glass could improve the structure and the crystallization,and reduce the conduction ability.关键词
钒酸盐玻璃/磷酸盐玻璃/氧化锑/氧化铋/体积电阻率Key words
vanadate glass/phosphate glass/antimonous oxide/bismuthous oxide/volume resistivity分类
化学化工引用本文复制引用
李宏彦,朱志梁,杨凤丽,庄卫东..Sb2O3部分替代V2O5对V2O5–P2O5–Sb2O3–Bi2O3体系玻璃电性能的影响[J].硅酸盐学报,2012,40(4):577-582,6.
