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0~20℃养护下硅酸盐水泥水化时钙矾石的生成及转变

王培铭 徐玲琳 张国防

硅酸盐学报2012,Vol.40Issue(5):646-650,5.
硅酸盐学报2012,Vol.40Issue(5):646-650,5.

0~20℃养护下硅酸盐水泥水化时钙矾石的生成及转变

Formation and Conversion of Ettringite During Hydration of Portland Cement from 0 to 20 ℃

王培铭 1徐玲琳 2张国防1

作者信息

  • 1. 先进土木工程材料教育部重点实验室,上海200092/同济大学材料科学与工程学院,上海200092
  • 2. 先进土木工程材料教育部重点实验室,上海200092
  • 折叠

摘要

Abstract

The formation and conversion of ettringite during the hydration of Portland cement cured at 0,5,10 and 20 ℃ were inves-tigated by X-ray diffraction and nuclear magnetic resonance,respectively.The results indicate that ettringite formed from 0 ℃ to 20 ℃ firstly increases and then decreases as the hydration time increases from 1 d to 180 d.The formation of ettringite varied with the curing temperatures.The content of ettringite formed reached a maximum either at 3 d at 10 ℃ and 20 ℃ or at 28 d at 0 ℃ and 5 ℃.For the curing age,however,the content of ettringite formed at 20 ℃(10.2%) exceeded that formed at other temperatures after 1 day,the content of ettringite formed at 10 ℃(12.1%) exceeded that formed at other temperatures after 3 d,and the content of ettringite formed at 0 ℃ from 3 d to 180 d was the highest.In addition,ettringite converted to monosulfate more slowly at lower temperatures.

关键词

低温养护/硅酸盐水泥/钙矾石/物相转变

Key words

low temperature curing/Portland cement/ettringite/phase conversion

分类

化学化工

引用本文复制引用

王培铭,徐玲琳,张国防..0~20℃养护下硅酸盐水泥水化时钙矾石的生成及转变[J].硅酸盐学报,2012,40(5):646-650,5.

基金项目

国家“十一五”科技支撑计划 ()

国家自然科学基金(51102182)资助 ()

硅酸盐学报

OA北大核心CSCDCSTPCD

0454-5648

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