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SDS/[C_nmim]Br/H_2O体系的双水相性质

陈婷 马爱青 王菲 尚亚卓 刘洪来

华东理工大学学报:自然科学版2012,Vol.38Issue(2):137-141,175,6.
华东理工大学学报:自然科学版2012,Vol.38Issue(2):137-141,175,6.

SDS/[C_nmim]Br/H_2O体系的双水相性质

Aqueous Two-Phase System(ATPS) Containing Ionic Liquids [C_nmim]Br and SDS

陈婷 1马爱青 2王菲 1尚亚卓 1刘洪来1

作者信息

  • 1. 华东理工大学化学系,化学工程联合国家重点实验室,上海200237
  • 2. 中石化胜利油田分公司采油工艺研究院,山东东营257000
  • 折叠

摘要

Abstract

Properties of mixed aqueous solutions of ionic liquid(Br) and traditional surfactant(SDS) were studied.Results showed that the properties of the mixed systems varied with the chain length of substituted alkyl in ionic liquids.Only those systems containing ionic liquids with equal to or more than 6 carbon atoms in alkyl chains can form aqueous two phase system(ATPS).The ATPS containing ionic liquids and surfactant has obvious extraction ability to xylenol orange and the potential to separate and purify biomaterials.The difference in appearance of ATPS should be attributed to the various size and shape of the surfactants aggregates formed in mixed solutions.Furthermore,the electrostatic attractive interaction,the hydrophobic interaction in addition to the synergistic effect between ionic liquids and SDS further promote the surfactant assembly,which leads to the formation of liquid crystal at lower surfactant concentration.

关键词

离子液体/表面活性剂/混合溶液/双水相/液晶

Key words

ionic liquids/surfactant/mixed solution/ATPS/liquid crystal

分类

数学

引用本文复制引用

陈婷,马爱青,王菲,尚亚卓,刘洪来..SDS/[C_nmim]Br/H_2O体系的双水相性质[J].华东理工大学学报:自然科学版,2012,38(2):137-141,175,6.

基金项目

国家自然科学基金 ()

教育部长江学者与创新团队计划(IRT0721)教育部留学回国人员科研启动基金 ()

中央高校基本科研业务费专项资金 ()

华东理工大学学报:自然科学版

OA北大核心CHSSCDCSCDCSTPCD

1006-3080

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