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气氛含氧量对DDT热处理特性的影响

李扬 王瑛 黄启飞 杨延梅

环境工程学报2012,Vol.6Issue(3):1051-1056,6.
环境工程学报2012,Vol.6Issue(3):1051-1056,6.

气氛含氧量对DDT热处理特性的影响

Effect of oxygen content on heat treatment characteristics of DDT

李扬 1王瑛 2黄启飞 3杨延梅3

作者信息

  • 1. 中国环境科学研究院,北京100012/重庆交通大学土木建筑学院,重庆400074
  • 2. 中国环境科学研究院,北京100012/西北农林科技大学资源环境学院,杨凌712100
  • 3. 重庆交通大学土木建筑学院,重庆400074
  • 折叠

摘要

Abstract

DDT is a kind of organochlorine pesticide,the DDTs in the pesticide are of hard-degradation and biological toxicity.In order to provide theoretical basis for developing high-temperature process on treating obsolete DDT,high temperature tube furnace was used to research the effect of oxygen content on heat treatment disposal characteristics of DDT.The results showed that,the destruction efficiency of DDT could reach 70.48% at 600℃ in the 21% oxygen atmosphere and be over 99% at 900℃ under the condition of 21% oxygen content only,at 1 200℃,it was over 99.9% when the oxygen content reached 12%.In the combustion residue,the percentage of o,p'-DDT in DDTs increased and the percentage of DDT reduced as the oxygen content rose under three temperature conditions,and the changes became distinct as the temperature increased.In the tail gas,the percentage of p,p'-DDE in DDTs increased as the oxygen content rose under three temperature conditions,and the phenomenon was more obvious at 1 200℃.

关键词

滴滴涕/POPs/热处理/含氧量

Key words

DDT/POPs/heat treatment/oxygen content

分类

资源环境

引用本文复制引用

李扬,王瑛,黄启飞,杨延梅..气氛含氧量对DDT热处理特性的影响[J].环境工程学报,2012,6(3):1051-1056,6.

基金项目

“十一五”国家科技支撑计划项目 ()

环境工程学报

OA北大核心CSCDCSTPCD

1673-9108

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