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Fenton试剂处理腐殖酸废水影响特性和降解动力学模型

吴彦瑜 周少奇

环境工程学报2012,Vol.6Issue(5):1435-1439,5.
环境工程学报2012,Vol.6Issue(5):1435-1439,5.

Fenton试剂处理腐殖酸废水影响特性和降解动力学模型

Influencing characteristics and kinetic model of humic acid degradation by Fenton's reagents

吴彦瑜 1周少奇2

作者信息

  • 1. 华南理工大学环境科学与工程学院,广州510006/环境保护部华南环境科学研究所,广州510655
  • 2. 华南理工大学环境科学与工程学院,广州510006
  • 折叠

摘要

Abstract

The influencing characteristics of Fenton's reagent on the degradation of humic acid(HA) wastewater were studied.The dynamics model was established based on the theoretical analysis of reaction process.The parameters of dynamics model were estimated according to the experimental data.The results showed that HA was removed both by oxidation and coagulation.Under operating conditions of initial pH 4,Fe2+ dosage of 40 mmol/L and H2O2 dosage of 160 mmol/L,reaction time of 60 min,78.6% and 11.5% removals for oxidation and coagulation were achieved,respectively,meanwhile the highest initial oxidation rate of 59.6 mg/(L·min) was achieved.The prediction of models was found to agree well with experimental results and confirm the proposed reaction mechanisms,which indicated that the oxidation degradation mechanism of HA accorded with the theory and practice of hydroxyl radicals.

关键词

腐殖酸/Fenton/氧化/混凝/动力学模型

Key words

humic acids/Fenton/oxidation/coagulation/kinetic model

分类

资源环境

引用本文复制引用

吴彦瑜,周少奇..Fenton试剂处理腐殖酸废水影响特性和降解动力学模型[J].环境工程学报,2012,6(5):1435-1439,5.

基金项目

“十一五”国家科技支撑计划项目 ()

广州市重大科技项目 ()

广东省教育厅人才项目 ()

环境工程学报

OA北大核心CSCDCSTPCD

1673-9108

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