含能材料2012，Vol.20Issue(3)：263-272,10.DOI:10.3969/j.issn.1006-9941.2012.03.001
新一代起爆药设计与合成研究进展
Development of a New-generation Primary Explosives Designing and Synthesis
盛涤伦 1朱雅红 1蒲彦利1
作者信息
- 1. 陕西应用物理化学研究所,陕西西安700061
- 折叠
摘要
Abstract
Nitrogen-rich heterocycle compounds are new generation primary explosives. They have excellent initiating and firing properties and enviroment friendship. The research key point is to design and synthesize the intermediates or ligands of nitrogen-rich heterocycle,nitrogen-rich heterocycle ligand complex compounds as well as their salt forms. The ligands of the new generation primaries are 5-nitrotetrazole (5-NT),5-hydrazinotetrazole (5-HT) ,1,5-diaminotetrazole (1,5-DAT) and triazoles. They all have the similar performances such as aromaticity,high heat of formation and high nitrogen content (61% -85%) which could be designed to high-energy insensitiveness primary explosives as complex cation,complexs anion and salts forms. Tetraammine bis(5-nitrotetrazolato) cobalt (III) perchlorate (BNCP) is already used in laser and semi-conductor bridge(SCB) detonators. Homologous compounds of BNCP (5-NT ligand based Ni/Cu/Zn) ,DAT ligand based Cu/Fe/Co/Ni complex cation and 5-NT ligand based ferrous/Cu/Co/Ni complex anion, hydrazinotetrazole or hydrazinotrizole ligand based Hg/Cu/Co/Ni/Cd and DTA ligand nitrate/perchlorate are widely researched. The typical primary explosives are [CuII(DAT)5(NO3)]NO3, (NH4)2[FeII(NT)4(H2O)2], (NH4)2[CuII(NT)4(H2O)2].关键词
有机化学/高能杂环化合物/配位化合物/起爆药/设计/合成Key words
organic chemistry/ energy-rich heterocycle compound/ coordination complexe/ primary explosive/ design/ synthesis分类
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盛涤伦,朱雅红,蒲彦利..新一代起爆药设计与合成研究进展[J].含能材料,2012,20(3):263-272,10.
