吉林大学学报（理学版）2012，Vol.50Issue(2)：346-350,5.
负载型磷钨酸催化剂的制备、表征及酯交换制备生物柴油
Preparation, Characterization of Supported Phosphotungstic Acid Catalyst and Its Application to Transesterification to Produce Biodiesel
摘要
Abstract
The supported phosphotungstic acid catalysts were prepared by loading phosphotungstic acid on the Worm-like mesporous carrier via the impregnation method. The supported catalysts and carrier were characterized by XRD, FT-IR, N2 adsorption-desorption and so on. The biodiesel was prepared by transesterification of castor oil and methanol with supported phosphotungstic acid as the catalyst. The conversion of transesterification was determined by the method of periodates oxidation. The effects of reaction parameters such as reaction temperature, time and n (methanol) :n( castor oil) on the transesterification were studied. At 55 °C, the ra( methanol) : n(castor oil) of 6, reaction time of 2 h, phosphotungstic acid loading of 50% , the conversion rate of transesterification was up to 95. 1 %.关键词
负载型磷钨酸/蓖麻油/酯交换/生物柴油Key words
supported phosphotungstic acid/ castor oil/ transesterification/ biodiesel分类
化学化工引用本文复制引用
徐玲,陈建军,张立明,刘宗瑞..负载型磷钨酸催化剂的制备、表征及酯交换制备生物柴油[J].吉林大学学报（理学版）,2012,50(2):346-350,5.基金项目
内蒙古自然科学基金(批准号:2011 BS0203)和内蒙古自治区高校蓖麻产业工程技术研究中心开放基金(批准号:BMYJ2011001). （批准号:2011 BS0203）
