煤炭转化2012，Vol.35Issue(2)：85-88,4.
钙基吸收剂碳酸化实验研究
STUDY ON THE CARBONATION REACTION OF Ca-BSASED ABSORBENT
摘要
Abstract
The reaction characteristics of CaO absorbing CO2 were investigated by discussing the influence of reaction conditions on the carbonated reaction and analyzing the dynamic property with unreacted shrinking core model. The results showed that the chemical reaction rate constant of the carbonation reaction is nearly a constant at 650 'C-750 'C; the product layer diffusion coefficient increasing with the increase of temperature; the activation energy of chemical reaction control section was E. = 29. 70 kJ/mol, and of the product control section was Ez = 92. 80 kJ/mol; with the volume fraction of CO2 increasing, the reaction rate and conversion rate increased.关键词
碳酸化/CaO/反应动力学/活化能Key words
carbonation/CaO/reaction kinetics/activation energy分类
化学化工引用本文复制引用
任斌,考宏涛,李爱莉..钙基吸收剂碳酸化实验研究[J].煤炭转化,2012,35(2):85-88,4.基金项目
国家重点基础研究发展计划(973)项目(2009CB623102)和中国科学院多相复杂系统国家重点实验室课题资助项目(MPCS-2011-D01). （973）
