南京工业大学学报（自然科学版）2012，Vol.34Issue(2)：111-113,132,4.DOI:10.3969/j.issn.1671-7627.2012.02.023
1,3,5,7-四甲基环四硅氧烷饱和蒸汽压的测定与关联
Measurement and correlation of saturated vapor pressure of 1,3,5,7-tetramethylcyclotetrasiloxane
摘要
Abstract
The temperatures of 1,3,5,7-tetramethylcyclotetrasiloxane were measured from 1.325 kPa to 100. 325 kPa by an inclined ebulliometer. The Antoine parameters of 1,3,5,7-tetramethylcyclotetrasiloxane were regressed by the nonlinear regression method with EVIEWS 5.0 software,A =8. 678 74,B = 1 167. 85, and C = -93. 579 K, respectivly. The correlation between the saturated vapor pressure and the temperature was conducted with the absolute deviation ranging from 0. 02 K to 1. 23 K. The mean molar enthalpy of vaporization of 1,3,5 ,7-tetramethylcyclotetrasiloxane was obtained from the Clausius-Clapeyron equation with a result of 41. 17 kj/mol. The calculated normal boiling point was 411. 5 K.关键词
1,3,5,7-四甲基环四硅氧烷/饱和蒸汽压/Antoine方程/平均摩尔蒸发焓Key words
1,3,5 ,7-tetramethylcyclotetrasiloxane/saturated vapor pressure/Antoine equation/mean molar evaporation enthalpy分类
化学化工引用本文复制引用
岳岩,董红,伍川,来国桥,蒋剑雄..1,3,5,7-四甲基环四硅氧烷饱和蒸汽压的测定与关联[J].南京工业大学学报（自然科学版）,2012,34(2):111-113,132,4.基金项目
教育部重点科研基金资助项目(208183) （208183）
浙江省自然科学基金资助项目(Y4090016) （Y4090016）
杭州市科技局科技创新基金资助项目(20090231102 （）
20100331 T17) （）
浙江省公益性技术应用研究计划项目(2011C21026) （2011C21026）
