南京师范大学学报：工程技术版2012，Vol.12Issue(1)：80-84,5.
廉价钙基载氧体煤化学链燃烧试验研究
Investigation of the Performance of Low-Cost Calcium-Based Oxygen Carrier in Chemical Looping Combustion of Coal
摘要
Abstract
Chemical-looping combustion（CLC） will be a very promising technology due to its high efficiency and low-cost for CO2 separation.In this paper,the reduction/oxidation characteristic as well as the cyclic performance of low-cost calcium-based oxygen carrier was investigated in a bench-scale fixed-bed reactor.The effect of temperature,operating pressure and coal/oxygen carrier mass ratio on the performance of calcium-based oxygen carrier were discussed.The results showed that increasing temperature and pressure can obviously enhance the reaction of calcium-based oxygen carrier with coal gasification products,which can lead to higher CO2 yield and carbon conversion.Such factors as the parallel reactions and the resistance of internal mass transfer in the oxygen carrier particles in practical reaction lead to inactivation of the oxygen carrier and the decrease of the oxygen carring ability.The coal/oxygen carrier mass ratio should be limited to 0.14 to get higher CO2 yield and carbon conversion.关键词
CO2捕集/煤化学链燃烧/钙基载氧体/固定床Key words
CO2 capture/chemical-looping combustion/calcium-based oxygen carrier/fixed-bed分类
能源与动力引用本文复制引用
施文平,肖睿,杨一超,张帅..廉价钙基载氧体煤化学链燃烧试验研究[J].南京师范大学学报：工程技术版,2012,12(1):80-84,5.基金项目
国家自然科学基金 （）
