燃料化学学报2012，Vol.40Issue(3)：326-330,5.
微波辐射下氯化锌催化纤维素转化为呋喃类物质的研究
Conversion of cellulose to furans catalyzed by zinc chloride under microwave irradiation
摘要
Abstract
Cellulose was degraded in concentrated ZnCl2 solution which acted as a solvent and catalyst under microwave irradiation. Cellulose was directly converted into two main furans, 5-hydroxymethyl furfural (5-HMF) and l-(furan-2-yl)-2-hydroxyethanone. Factors affecting the mol yields of these two compounds were investigated at different temperatures, reaction times, concentrations of ZnCl2, cellulose contents, and microwave powers. For 1 g cellulose reacted with 140 tnL 69% ZnCl2 solution, the mol yields of 5-HMF reached to 19.4% under the microwave power of 500 W and l-( furan-2-yl) -2-hydroxyethanone reached to 12.0% under the microwave power of 600 W at 135 ℃ within 5 min.关键词
纤维素/氯化锌/微波/5-羟甲基糠醛/1-(2-呋喃基)-2-羟基-乙酮Key words
cellulose/ZnCl2/microwave/5-HMF/1-( furan-2-yl)-2-hydroxyethanone分类
化学工程引用本文复制引用
杨磊,黎钢,杨芳,刘雅莉,张松梅..微波辐射下氯化锌催化纤维素转化为呋喃类物质的研究[J].燃料化学学报,2012,40(3):326-330,5.基金项目
国家自然科学基金(20876032) （20876032）
天津市应用基础及前沿技术研究计划重点资助项目(IIJCZDJC23600) （IIJCZDJC23600）
河北省应用基础研究计划重点基础研究项目(11963924D). （11963924D）
